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As the journey continues, there's beauty and danger in equal measure. Charley and Ewan travel through the extraordinary Bolivian desert, but the sandy roads make all more difficult. The duo ride their electric bikes through the exotic and breathtaking countryside and all the way making a challenging ascent. The riders stay in a hotel made entirely out of salt before heading to La Paz. 'Bolivia' also shows some quality work done by UNICEF when it comes to educating and working with the children. McGregor and Boorman spend time with the kids before resuming their journey and ending with a ferry ride over lake Titicaca.

Ewan and Charley make their way to Peru from Bolivia, and the scenery is just beautiful. Ewan wanted to visit Machu Picchu since he was a kid and decides to show the world the Incan citadel set high in the Andes Mountains. Next up, they make their way to the Cutivireni, a community of Ashaninka people in the Amazon rainforest, with its carbon program to limit the magnitude or rate of global warming and its related effects.