We are the only species on earth that cooks its food - and we are also the cleverest species on the planet. The question is: do we cook because we're clever and imaginative, or are we clever and imaginative because our ancestors discovered cooking? Horizon examines the evidence that our ancestors' changing diet and their mastery of fire prompted anatomical and neurological changes that resulted in taking us out of the trees and into the kitchen.

Just 92 elements made up the world, but the belief that were only four - earth, fire, air and water - persisted until the 19th Century. Professor Al-Khalili retraces the footsteps of the alchemists who first began to question the notion of the elements in their search for the secret of everlasting life.He reveals the red herrings and rivalries which dogged scientific progress, and explores how new approaches to splitting matter brought us both remarkable elements and the new science of chemistry.

In this programme, Mary descends into the city streets to discover the dirt, crime, sex and slum conditions in the world's first high-rise city. This Rome is not the marble Rome we know, but a vast, messy metropolis with little urban planning, where most Romans lived in high-rise apartment blocks with little space, light, or even sanitation. Forced outdoors into the city streets, she reveals where they went to hang out, get drunk, have sex and get clean. She looks at the Forum as a place of gamblers, dentists and thieves, and she explores the lustiness of Roman bar life and jokes. Finally, exploring law and order from the bottom up, Mary examines how this city really worked. She meets Ancarenus Nothus, an apartment dweller who lived in fear of the rent collector; Notorious Primus, who wrote about his three great pleasures in life - baths, wine and sex; and Unlucky Doris, a seven-year-old girl killed in one of Rome's many fires.

Iain explores man's relationship with fire. He begins by embarking on an extraordinary encounter with this terrifying force of nature - a walk right through the heart of a raging fire. Fire has long been our main source of energy and Iain shows how this meant that the planet played a crucial role in Britain's industrial revolution, whilst holding China's development back. Along the way he dives in a mysterious lake in Oregon, climbs a glacier of salt, crawls through an extraordinary cave in Iran and takes a therapeutic bath in crude oil.

Long ago, two species of human beings coexisted on Earth until competition drove one of them to extinction. This program, set in the southwest of France 35,000 years ago, reconstructs the life in the Neanderthal world at the time Cro-Magnons first entered the scene. All aspects of Neanderthal clan life are examined, including tool- and weapon-making, hunting and gathering, health and healing, childbirth, rituals, and making fire. Footage of skeletal remains and the scholarly research of eminent paleontologist Chris Stringer and Oxford University's Paul Pettitt support the documentary.

As he tries his hand at baking, brewing and braising, acclaimed food writer Michael Pollan explores how cooking transforms food and shapes our world. In the first espisode, with help from Aboriginal hunters and a barbecue pit master, Pollan shows how fire shaped human gastronomy, and weighs our duty to the animals we eat.