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Just about every solid, liquid, or gas in the world as we know it begins with reactions between individual atoms and molecules. Host David Pogue dives into the transformative world of chemical reactions, from the complex formula that produces cement to the single reaction that’s allowed farmers to feed a global population by the billions.

Targeting unsuspecting Americans, a group of payday lenders made millions off small loans with undisclosed charges, inflated interest rates and incomprehensible rules. But the way the laws are written, is that a crime or just business?

'Mormon Lost Boys' Young men have been thrown out of their homes because of an edict allowing polygamist church elders to monopolize young girls. 'The Fat Farms of Mauritania' In the West African country of Mauritania, parents send their daughters to rural fattening camps. 'Mumbai Slumscraper' A visit to Mumbai, where slums sit below billion-dollar, single-family skyscrapers.

The theory of Némesis, a star that orbits the Sun and causes catastrophic events is explored. Nemesis is a hypothetical red dwarf or brown dwarf, originally postulated in 1984 to be orbiting the Sun at a distance of about 95,000 AU (1.5 light-years) somewhat beyond the Oort cloud, to explain a perceived cycle of mass extinctions in the geological record, which seem to occur more often at intervals of 26 million years.

This episode tells the story of the Jewish Revolt, which swept through Judea in AD 66 and threatened to destabilise the whole empire. Rome turned to the disgraced General Vespasian and his son Titus to put it down. Filled with spectacular sieges and huge set-piece action, the film pits the discipline and ingenuity of the Roman army against the passion and commitment of the rebels.

In 1927, Prohibition agent Eliot Ness narrowly escapes a hit ordered by Al Capone. Determined to prove to Capone that he's not intimidated, Ness and his team of Untouchables execute a series of high-profile raids on Capone's breweries. Over the course of a few months, they destroy more than 200,000 gallons of beer, worth a modern-day equivalent of $134 million - and the newspapers cover it all. Capone lashes out against Ness in the press. What Capone doesn't realize is that Ness and the Prohibition agents aren't the only ones trying to take him down. For the past four years, another government agency with more manpower and resources than Ness has been going after the infamous kingpin: the Internal Revenue Service.